Metallaphotoredox-catalyzed C–H activation: regio-selective annulation of allenes with benzamide
نویسندگان
چکیده
We have developed an efficient annulation of benzamides with allenes using cobalt and photoredox dual catalysis under oxygen atmosphere. The transformation features alternative strategy for the regeneration a catalyst aid Eosin Y.
منابع مشابه
Regio- and Stereoselective Oxysulfonylation of Allenes.
A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical p...
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ژورنال
عنوان ژورنال: Organic chemistry frontiers
سال: 2021
ISSN: ['2052-4110', '2052-4129']
DOI: https://doi.org/10.1039/d0qo01127d